منابع مشابه
(Benzophenone imine-κN)chlorido(hydridotripyrazolylborato)(triphenylphosphine)ruthenium(II) diethyl ether solvate
The reaction of RuCl(Tp)(Ph(3)P)(2), where Tp is [(CH)(3)N(2)](3)BH, with benzophenone imine leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(13)H(11)N)(C(18)H(15)P)]·C(4)H(10)O. The environment about the Ru atom corresponds to a slightly distorted octa-hedron and the bite angle of the Tp ligand produces an average N-Ru-N angle of 86.3 (9)°. The three Ru-N(Tp) bond lengths ...
متن کاملHazard assessment of benzophenone [Benzophenone, CAS No. 119-61-9] Generic name: Benzophenone Synonyms: Diphenylmethanone, Diphenyl ketone, Benzoylbenzene, BZP
Vapor pressure: 1.33×10 Pa (108.2°C) Partition coefficient: Log Pow = 3.18 (observed value) Degradability: Hydrolyzability: No Report Biodegradability: Poorly biodegradable (BOD=0%, 14 days) Solubility: Water: 137 mg/l (25°C) (observed value) Organic solvents: Soluble in acetone and benzene. Amount of production/import:(1998): 322 t (Production 0 t, Import 322 t) Usage: Raw material for synthes...
متن کاملScreening of benzophenone imines
New series of benzophenone imines with general formula Ph2-C=NR; R = Benzyl, 4-Fluorobenzyl, Naphthyl, Phenyl, 4-Nitrophenyl were synthesized by condensation of dichlorodiphenylmethane and different aromatic primary amines (1:1) Those imines were characterized by different physiochemical and spectroscopic techniques like melting point, elemental analysis, FT-IR, multinuclear NMR (H, C). After c...
متن کاملTitanium(IV) imido complexes of imine imidazol-2-imine ligands.
Free imine imidazol-2-imine ligands with two different substitution patterns have been isolated for the first time and they were found to exist as an equilibrium mixture of geometric and mesomeric isomers. The relative ratios of these isomers are dependent on both the nature of the substituents and of the solvent. The synthesis of the titanium(IV) alkyl and arylimido complexes of these ligands ...
متن کاملImine hydrogenation by alkylaluminum catalysts.
Di-isobutylaluminum hydride and tri-iso-butylaluminum (DIBAL 1, TIBAL 2) are shown to be efficient hydrogenation catalysts for a variety of imines at 100 °C and 100 atm of H2, operating via a hydroalumination/hydrogenolysis mechanism.
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ژورنال
عنوان ژورنال: Synlett
سال: 2006
ISSN: 0936-5214,1437-2096
DOI: 10.1055/s-2006-949619